This website has many screenshots ( SciFinder1, SciFinder2, ChemSpider) that illustrate these approaches with many examples. are used to narrow the list to one structure. Other ancillary information such as mass spectral fragments in EI or CID spectra isotopic abundances, UV spectra types of ion adducts CI data number of exchangeable protons etc. The candidate structures from the CAS Registry or ChemSpider searches are prioritized by either the number of associated references or key words. We had originally used this approach to search the TSCA database or our Eastman Chemical plant material listing. We define them as “spectra-less” databases because they contain no computer-searchable mass spectral data. This data is used to search very large databases such as the CAS Registry or ChemSpider via web interfaces. “Spectra-Less” Database Searching: If the NIST search is not successful, then accurate mass data is used to obtain a molecular formula (MF), a monoisotopic mass, or an average molecular weight. The NIST search interfaces easily with a wide variety of manufacturers’ data processing and structural drawing programs: We use the NIST and Wiley commercial databases, but there are many other specialty databases that others might find useful. MoNA EI and Tandem Libraries in NIST format The MoNA “crowd-sourced” libraries in NIST EI and Tandem formats are found at the following link: We employ both purchased, in-house, and “crowd-sourced” libraries. The computer EI searches normally work better than CID ones, but the latter are still very useful. I have developed two free “webinar” series courses that detail the use of the NIST search with EI and tandem libraries for the identification of unknowns: NIST Search of EI and CID Spectra: The initial step in our process utilizes computer searches of EI (GC-MS) or CID (LC-MS) spectra against reference databases using the NIST MS search. The “spectraless” ones are discussed at the bottom of this post. The approach uses either NIST libraries or “spectraless” databases such as the CAS Registry or ChemSpider. The article originated from work presented at Pittcon in 2012. This process is described in detail in the February 2013 copy of LCGC, “MS-The Practical Art.” The article is entitled: “Identifying “Known Unknowns” in Commercial Products by Mass Spectrometry.” A copy with associated ads is shown below: The process is shown in the following simplified flowchart: We define “known unknowns” as non-targeted species which are known in the chemical literature or mass spectrometry reference databases, but unknown to the investigator. Introduction: In the last 34 years, we have developed a systematic process for the identification of “known unknowns” by GC-MS and LC-MS in commercial products. Note: Details on other subjects are found in “My Topics” tab under sailboat picture above or on the sidebar links to the right. Systematic Process for the Identification of “Known Unknowns” in Commercial Products by GC-MS and LC-MS : “Approaches for Identifying New Psychoactive Substances (NPS)” at 2023 Current Trends in Seized Drugs Analysis Symposiumġ1/01/22: Training for Wiley KnowItAll New EI Mass Spec Capabilities : FREE Courses for GC-MS and LC-MS Identifications Using NIST Search SoftwareĤ/27/23: NIST2023 Libraries and Software Available in Early June
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La-La Land got its share of the pie as well, releasing famous scores, both from the Paramount catalog and other rightholders, titles such as Innerspace, I.Q. The release of Elmer Bernstein’s Airplane! opened a breach for all film music labels to use, offering fans numerous scores they wished for in vain for ages. In 2009, La-La Land has finally secured his place in the pantheon of specialized labels, gaining access to the Paramount Pictures archives deemed inviolable for decades. At first mostly issuing or reissuing scores from horror movies ( Re-Animator, From Beyond, Creepshow or Christopher Lennertz’s Saint Sinner), the small label has gradually grown and gained a well-deserved place amongst the bigger players such as Varèse Sarabande, Film Score Monthly and Intrada. At the end of 2002, film music aficionados discovered in their favorite record stores or on the internet the CDs from a new, small label: La-La Land Records. “Also, make sure you sign your return before sending,” said financial advisor and professional tax preparer Rob Burnette of Outlook Financial Center. An unsigned tax return isn't valid, the IRS says. 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Sometimes returns are selected at random for a closer review.Ī lot of audit notices the IRS sends are automatically triggered if, for instance, your W-2 income tax form indicates you earned more than what you reported on your return, said Erin Collins, National Taxpayer Advocate at the Taxpayer Advocate Service division of the IRS. When you're audited by the IRS, it means your return was selected from a batch of returns for a closer inspection. In both instances, just make sure you mark your contributions for the 2022 tax year. Total combined contributions for both traditional and Roth IRAs are capped at the smaller of $6,000, or $7,000 if you’re age 50 or older by the end of the year or your taxable compensation for the year, the IRS said.įilers may also add funds to their health savings account (HSA), if they are eligible for one, to count toward 2022. 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Season 6 of 'Growing Up Hip Hop' included some massive changes in the cast lineup. Jamie Foxx and Datari Turner Executive Produce for Foxxhole Productions alongside Executive Producers Antney and Nikaya D. Bev is Boss pulls back the curtain on my personal journey and invites the world to experience each step along the way.” Working with Jamie and his team to bring my story to life has been deeply rewarding on a professional level. Growing Up Hip Hop season 7 will air Thursdays at 9 p.m. “However, it’s where I needed to go creatively to tell this uniquely personal story. “Being vulnerable and letting others in isn’t exactly a comfortable place for me,” said Antney. Her story will unfold over an eight-episode season this summer on WE tv. Growing Up Hip Hop 1 season Reality 2023 English audio TV-14 Try ALLBLK free Buy Growing up with a famous parent isn't easy, as the children often have to work hard to emerge from their. She is the mother of acclaimed rapper Waka Flocka Flame and is infamous for her ‘no holds barred’ approach to the business.Īntney serves as executive producer and, during series development, candidly shared her life experiences, an audacious yet bracingly rare occurrence in the business of entertainment. The series will debut this fall, exclusively on WE tv and sister streamer ALLBLK.īev is Boss is a scripted drama that will follow the career of Deb Antney, who rose to fame for breaking the careers of several high-profile artists, such as Gucci Mane, French Montana and Nicki Minaj. “I’m so excited to let viewers back into our lives to see what my family has been up to since you’ve seen us last,” Johnson-Rushing said in a statement. (WE tv) The Growing Up Hip Hop star spent the final months of her pregnancy quarantined in New York amid the coronavirus pandemic. Gina Miles: 5 Things To Know About ‘The Voice’ Standout Who Is Just 18 Click to Subscribe to Get Our Free HollywoodLife Daily Newsletter to get the hottest celeb news.WEtv Programming Chief Lauren Gellert Exits Eric and Layzie visit Eazy-E’s gravesite, but rumors around his death must be put to rest.” Growing Up Hip Hop airs Thursdays at 9 p.m. Treach supports Egypt’s music career while Sam faces serious prison time. The synopsis for the February 3 episode of Growing Up Hip Hop season 6 reads: “A surprise bachelor and bachelorette party for Tee Tee and Shawn ends in disaster. And we can thank Madina Milana for most of that drama. Growing Up Hip Hop Atlanta Season 2 Episode 14 - Too Lit to Quit Growing Up Growing Up Hip Hop Atlanta Lattest episode. In the years since his death, there have been conspiracy theories that foul play could have been involved. 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Make sure to restart your computer if prompted. MixMeister Express Demo: This is a fully-functional trial version for 15 days with no other limitations. MixMeister Express is a powerful tool that you can use to create a professional-sounding mix from your music files with a minimum of effort. MixMeister is considered to be one of the most reliable providers of digital music technology and this package is only a single component of their other software downloads. Follow the on-screen instructions to install Mixmeister. Sell MixMeister Fusion for 50, include a few of the standard DJ effects and market the AIR effects as a premium addon. It’s not worth the same as them, and none of the DJ apps cost much more than 100. The main benefit is that the majority of music files contain no information in regards to beats per minute, so this bundle takes the guesswork out of the equation. MixMeister can’t compete with DAWs like Ableton and Bitwig, because it isn’t them, either in features or reputation. All of these functions are commonly employed by DJs and other digital music technicians. MixMeister BPM Analyzer can be used to mix disparate tracks, to build a playlist or to compare the beats between two different songs. It can be employed to calculate the length of a file or to integrate other elements (such as different instruments) within an existing track without compromising rhythm. MixMeister BPM Analyzer is an application that is often used by musicians who are looking to determine the tempo of a song (the number of beats per minute). Take it with you.You can bring your mix along wherever you go, by exporting your creation to leading portable audio players, including iPod, Rio, iRiver, Creative Labs, Philips, Samsung, and other models which support playback or conversion of WMA files.Mireia Fernandez Cristia Updated 2 years ago Professional software to detect the number of beats per minute within a song MixMeister Express also has integrated CD burning capabilities, so creating your own mix CD is a snap. You can even prepare some of the mix in advance, and change it on the fly. MixMeister Express Versión de prueba 3 (86 votos) Crea fantásticas mezclas de música de forma muy sencilla Con MixMeister Express puedes realizar atractivas mezclas de audio, como un auténtico DJ profesional, en apenas unos minutos y sin necesidad de ser un experto en el tema. If you're throwing a party, you can give MixMeister the job of spinning the tunes. Express is used every day by dance music fans, party DJs, fitness instructors and choreographers who want to let the computer do the hard parts and make their. Whether you're creating a mix for a dance floor or a group fitness class, you can adjust the beats per minute to heat people up or cool them down. With MixMeister Express, it’s easy to make a song faster or slower to achieve the exact tempo you want. You can use the one-click transition settings as a starting point for your creation, or, if you're a more advanced user, you'll be able to add your own tweaks and touches. MixMeister Express greatly simplifies this process by automatically calculating how to beat mix between songs. You can sew tracks together just like in MixMeister, but Ableton has a much better timestretching algorithm. ago No problem It probably doesn’t and even if it did the UX would be terrible anyway 1 Reply PoodlyDoodly 5 yr. One of secrets to creating a great mix CD is getting the overlap between songs just right. It is sad that MixMeister no longer supports the latest version of the Mac. Since our inception in 2000, weve earned a. Create a full-length mix CD (up to 80 minutes), and export your DJ mix to your iPod or other portable audio player.īlend your beats. At MixMeister Technology, we create innovative software tools for playing, producing and performing music mixes.Add one-click special effects for even more fun ways to blend songs together.Trim long songs down to size or remix short songs to make them last longer.Make a song slower or faster to achieve the tempo you need, without changing pitch.Create professional-quality mixes, with beat-mixed transitions between songs that sound great.Express is used every day by dance music fans, party DJs, fitness instructors and choreographers who want to "let the computer do the hard parts" and make their own mix CD in minutes. 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There's a built-in headphone socket for audio monitoring, and rear control dial gains touch-sensitive 'buttons' that allow recording parameters (shutter speed, aperture, ISO and sound volume) to be changed silently. In terms of ergonomics, the camera gains the 7D's rear movie mode/live view switch, so you no longer have to compromise your stills Live View settings when setting up for video recording. Movie mode turned out to be the 5D Mark II's trump card over its rivals, and its successor naturally offers improved capability in this regard. And let's not forget that 61-point focus system from the 1DX - the first time Canon has put its top-spec AF sensor into a non-1-series camera since the film-era EOS 3. Viewfinder coverage is a full 100%, and the 1040k dot, 3:2 aspect ratio 3.2" LCD screen has improved anti-reflection properties and a hardened glass cover to protect against scratching. The shutter is rated to 150,000 cycles and has been refined for quieter operation the Mark III also inherits the 'silent' shutter mode previously seen on the 1D-series. An 8-channel sensor readout enables continuous shooting at 6 fps. The new sensor, coupled with Canon's latest DIGIC 5+ processor, offers a standard ISO range of 100 - 25,600 that's expandable to 50 - 102,800. Most of the key specs are substantially upgraded compared to the 5D Mark II. 1080p30 video recording, stereo sound via external micĬanon EOS 5D Mark III and II key differences. Read on to find out out how the 5D Mark III performs in our studio and real-life tests, how we liked its handling and operation and if it is the right camera for your requirements and type of photography. But it also gains a raft of additional tweaks and improvements in response to customer feedback these range from dual slots for CF and SD cards, through a locking exposure mode dial, to a large depth of field preview button that's repositioned for right-handed operation, and can be reprogrammed to access a number of other functions. In a way it's better seen as a full-frame 7D, with that camera's control layout, extensive customizability and 63-zone metering sensor. Indeed the 5D name itself is almost misleading compared to its predecessor the Mark III is essentially a completely new model, with every major system upgraded and updated. But for those whose glasses tend more towards the half-full, it might just turn out to be the camera that 5D Mark II owners always really wanted. From the glass-half-empty point of view, this could be seen as an unambitious update that trails disappointingly behind Nikon's 36MP D800 which was announced around the same time. The 5D Mark III has a 22MP full frame sensor in a body that's based on the EOS 7D design, and with a 61-point AF system borrowed from the flagship EOS-1D X. On the face of it, though, the latest model offers little that looks likely to make the same impact. The 5D Mark II was the first SLR capable of recording full HD video, a feature that revolutionized the market in a fashion that no one could possibly have envisaged at the time - least of all Canon. The original EOS 5D of 2005 was the first 'affordable' full frame SLR, and the camera that cemented the 24x36mm sensor as the format of choice for many professional applications at a time when many were questioning its continued relevance. Up until now, the 5D series has been a dynasty of slightly unlikely revolutionaries. Now, 25 years later, the Canon EOS 5D Mark III is the latest model in the line. With its fully-electronic lens mount, in-lens aperture and focus motors, and reliance on electronic button and dial operation, Canon's EOS system established a blueprint that all successive camera systems have followed. It was the Japanese manufacturer's first 35mm autofocus SLR and the start of the EOS system. In 1987 Canon unveiled the EOS 650 to the world. |